A molecular orbital examination (CNDO/2) of the importance of fluorine hyperconjugation

✍ Scribed by D. Holtz; A. Streitwieser Jr.; R.G. Jesaitis

• Book ID: 104240068
• Publisher: Elsevier Science
• Year: 1969
• Tongue: French
• Weight: 196 KB
• Volume: 10
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)88742-6

✦ Synopsis

Received in UsA P&d Sep+ember 1969; raceived in IW for @licetion 7th *to-1969) Fluorine hyperconjugation has been cited as a factor in the stabilization of fluoro anions (1,2). For example, in the 2-fluoroethyl anion we oan draw the resonance forms: