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A Modular Approach to Oxoindolizino Quinolines: Efficient Synthesis of Mappicine Ketone (Nothapodytine B)

✍ Scribed by Gajendra B. Raolji; Stéphanie Garçon; Andrew E. Greene; Alice Kanazawa

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
108 KB
Volume
115
Category
Article
ISSN
0044-8249

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## Abstract Treatment of 2‐hydroxy‐, 2‐mercapto‐, and 2‐ethoxycarbonylamino‐benzonitriles **12** with 2‐fluoro‐ or 2‐nitrophenacylbromides **13** under alkaline conditions provided the corresponding benzofuran, benzothiophene, and indole intermediates **10**, respectivelly. Nucleophilic cyclization