Formation of a high valent di-μ-oxo mang
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Rajesh Manchanda; Gary W. Brudvig; Robert H. Crabtree; Joseph E. Sarneski; Mary
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Article
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1993
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Elsevier Science
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English
⚖ 291 KB
We find an unusual example in which different clusters can be isolated from the same reaction mixture depending on the choice of counter-ion. The complex [(bipy),Mn(III)(~-O),Mn(IV)(bipy),]3+ (1 is isolated from Mn(II) and permanganate in acetate buffer with C104-, but [(blpy)(H,O)Mn(III)(~-O)(p-