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A model study on the mechanism of inhibition of fatty acyl desaturases by cyclopropene fatty acids

✍ Scribed by Jordi Quintana; Mireia Barrot; Gemma Fabrias; Francisco Camps

Book ID
108379064
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
701 KB
Volume
54
Category
Article
ISSN
0040-4020

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In relation to the mechanism of fatty acid synthetase inhibition by cerulenin (1) the reaction between this antibiotic and thiols were studied. The structures of the propanethiol adduct 2 and of the cysteine methyl ester adduct 3 were determined to be respective (2S, 3R)-2Ialkylmercapto-3-hydroxy de