A model for the unsaturated intermediate in dissociative electron-transfer catalyzed substitution reactions of organometallic compounds
β Scribed by Donovan, Bernadette T.; Geiger, William E.
- Book ID
- 121274864
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 929 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Utilization of a triptoxy radical probe in the with 2,3,3-trimethyl-2-butyl peroxybenzoate indicates reaction decreases in the order B-BuLi>B-BuMgCl>PhMgBr. reactions of organometallic compounds that the radical character of the Peroxides may react with nucleophiles either by nucleophilic displaceme
In the present work we have carried out a Monte Carlo simulation of a dissociative electron transfer reaction in a polar solvent. In particular, we have chosen as a very simple model the electrochemical reduction of hydrogen fluoride to give a hydrogen atom and a fluoride anion in a dipolar solvent.