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A model for metabolic activation of dialkylnitrosamines. Oxidative dealkylation of 2-(N-nitrosoalkylamino)acetonitriles by a flavin mimic in aqueous solution

✍ Scribed by Yano, Yumihiko; Yokoyama, Takeshi; Ikuta, Masato; Yoshida, Kitaro

Book ID: 125986908
Publisher: American Chemical Society
Year: 1987
Tongue: English
Weight: 612 KB
Volume: 52
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00234a018

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A model for metabolic activation of dial

A model for metabolic activation of dialkylnitrosamines. Oxidative dealkylation of N-nitroso-2-(alkylamino)acetonitrile by flavin mimic in aqueous solution

✍ Yumihiko Yano; Takeshi Yokoyama; Kitaro Yoshida 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 232 KB

Oxidation-active flavin mimic, benzo[l,2-g, 5,4\_g']dipteridine (BDP), is found to react with N-nitroso-2-(alkylamino)acetonitrile via oxidative dealkylation in aqueous solution. From the kinetic investigations, the oxidation mechanism is proposed.