✦ LIBER ✦

A model for highly para-selective reactions in HZSM-5 zeolite catalyst

✍ Scribed by Wugeng Liang; Songying Chen; Shaoyi Peng

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 416 KB
Volume: 50
Category: Article
ISSN: 0009-2509
DOI: 10.1016/0009-2509(95)00095-m

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✦ Synopsis

A theoretical model incorporating diffusion and reaction which takes place via the adsorbed state is proposed for highly p-xylene selective catalysts. Based upon the measured values of diffusivities, adsorption equilibrium constants and reaction rate constants, the modified model is used to explain and predict the high para-selectivities in toluene disproportionation and xylene isomerization. The agreement between theory and experiment is good.

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