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A mixed valent iron glycinate with the kagome structure

✍ Scribed by Meenakshi Dan

Book ID: 103836594
Publisher: Elsevier Science
Year: 2004
Tongue: English
Weight: 282 KB
Volume: 706
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2004.02.054

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✦ Synopsis

An iron glycinate of the composition [Fe

containing Fe in both þ 2 and þ3 oxidation states has been obtained hydrothermally. The compound has a perfect kagome structure, with a typical hexagonal tungsten bronze-type sheet. The compound shows divergence between the zero-field-cooled and the field-cooled samples in the magnetization data and exhibits ferromagnetism at low temperatures. These magnetic properties are entirely different from those of ordinary Fe(III) kagome structures.

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