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A MINDO/3 study of CN bond rotation in methyleneamine n-oxide; A concerted rotation-pyramidalization pathway

✍ Scribed by W.Brian Jennings; S.D. Worley


Book ID
104244181
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
213 KB
Volume
18
Category
Article
ISSN
0040-4039

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A 13C NMR study of hindered rotation in
✍ Iwona Wawer 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 388 KB

Rates of rotations about the C-N' partial double bond in a series of six N',N' penta-and six N',N'-hexa-methylene-Nz-substituted-phenyformamidines were determined from 13C DNMR line shape analysis. Electron accepting substituents at the phenyl ring increase the barrier to rotation, and electron don