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A mild oxidative decarboxylation of carbohydrate acids

✍ Scribed by Cosme G. Francisco; Concepción C. González; Ernesto Suárez

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
292 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The oxidative decarboxylation of carbohydrate uranic or ulosonic acids with simultaneous replacement by an acetoxy group has been accomplished using the (diacetoxyiodo)benzene and iodine system under mild conditions. A general synthesis of derivatives of tetrodialdoses, and pentodialdoses in furanose or pyranose form is described.

📜 SIMILAR VOLUMES

Oxidative decarboxylation of cyclohexane
Oxidative decarboxylation of cyclohexanecarboxylic acid
✍ J. A. Bigot; P. L. Kerkhoffs 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 273 KB

## Abstract Cyclohexanecarboxylic acid is converted to a mixture of cyclohexanone and cyclohexene by reacting it at temperatures around 200° with an oxygen‐containing gas and steam in the presence of metal‐salt catalysts.