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A Mild, Convenient, and Inexpensive Procedure for Conversion of Vinyl Halides to α-Haloketones

✍ Scribed by VanBrunt, Michael P.; Ambenge, Reuben O.; Weinreb, Steven M.


Book ID
120645742
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
85 KB
Volume
68
Category
Article
ISSN
0022-3263

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A Mild, Convenient, and Inexpensive Proc
✍ Michael P. VanBrunt; Reuben O. Ambenge; Steven M. Weinreb 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 151 KB

A Mild, Convenient, and Inexpensive Procedure for Conversion of Vinyl Halides to α-Haloketones. -Reaction of vinyl chlorides (I) with sodium hypochlorite in acidic solution provides an efficient access to α-chloroketones (II). Analogously, the vinyl bromides react with freshly prepared sodium hypobr