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A mild and selective cleavage of tert-butyldimethylsilyl ethers by indium(III) chloride

✍ Scribed by Yadav, Jhillu S.; Subba Reddy, Basi V.; Madan, Chinnala


Book ID
118202604
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
101 KB
Volume
24
Category
Article
ISSN
1144-0546

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Cleavage of tert-butyldimethylsilyl ethe
✍ Jaume FarrΓ s; Carme Serra; Jaume Vilarrasa πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 181 KB

A general method for the selective cleavage of tert-butyldimethylsilyl ethers in the presence of tert-butyldiphenylsilyl ones has been established using a combination of H20 and a concentrated solution of LiCI in DMF at 90 Β°C. Since no acids, bases, reducing or oxidizing agents are used, the method