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A Mild and Highly Convenient Chemoselective Alkylation of Thiols Using Cs2CO3—TBAI.

✍ Scribed by Ralph Nicholas Salvatore; Robert A. Smith; Adam K. Nischwitz; Terrence Gavin

Publisher
John Wiley and Sons
Year
2006
Weight
30 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Mild and efficient synthesis of thiocarb
Mild and efficient synthesis of thiocarbonates and thiocarbamates via a three-component coupling utilizing Cs2CO3 and TBAI
✍ Ralph N Salvatore; Suma Sahab; Kyung Woon Jung 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 62 KB

The presence of cesium carbonate and tetrabutylammonium iodide (TBAI) facilitated efficient thiocarbonylation of alcohols, and thiocarbamation of amines, using carbon disulfide with alkyl halides. This protocol was mild, chemoselective, and efficient, compared to the existing methods.