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A Mild and Efficient Procedure for Ring-Opening Reactions of Piperidine and Pyrrolidine Derivatives by Single Electron Transfer Photooxidation

โœ Scribed by Guillaume Cocquet; Clotilde Ferroud; Alain Guy


Book ID
108370753
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
299 KB
Volume
56
Category
Article
ISSN
0040-4020

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Ring opening in the reaction of diphenyl
โœ Gernot Boche; Michael Marsch ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

The reaction of cyclopropanes like 2,3,4-triphenyl-endo-tricyclo[3.2.1.02'0]octane (la) with base is initiated by proton and not by ele$trov transfer. The facile disrotatory cyclopropyl anion ring opening reaction of 2JR2=CN, M =Ll ) at -75ยฐC does not occur synchronously. 2,3,4-Triphenyl-endo-tricyc