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A mild and efficient method for the formation of allylstannanes utilizing SmI2-induced polarity inversion of π-allyl palladium complexes

✍ Scribed by Takanori Tabuchi; Junji Inanaga; Masaru Yamaguchi

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
154 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

Palladium-catalyzed reduction of allylic acetates with Sm12 in the presence of R3SnC1 proceeded at room temperature to afford the corresponding allylstannanes in good yields.

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