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A Mild and Efficient Method for N-Arylnucleobase Synthesis via the Cross-Coupling Reactions of Nucleobases with Arylboronic Acids Catalyzed by Simple Copper Salts

✍ Scribed by Lan Tao; Yang Yue; Ji Zhang; Shan-Yong Chen; Xiao-Qi Yu


Publisher
John Wiley and Sons
Year
2008
Tongue
German
Weight
176 KB
Volume
91
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

A simple and efficient copper‐salt catalyzed N‐arylation of nucleobases is reported. In a mixed solvent of MeOH and H~2~O, the coupling products were obtained in moderate to excellent yields at room temperature within a short time. A variety of substituted N‐aryl nucleobases can be prepared through this procedure.