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A method of studying the anisotropic rotation of organic nitroxyl radicals

✍ Scribed by A.N. Kuznetsov; A.Y. Volkov; V.A. Livshits; A.T. Mirzoian

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
373 KB
Volume
26
Category
Article
ISSN
0009-2614

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✦ Synopsis

A method of "additional broadening" is proposed that permits the measuring, with a minimal error, of rotational correlation times together with the degree of anisotropic rotation (DAR) of nonspheroidal organic nitroxyl radicals in the rapid motion rqion, in isotropic media. Using this method, it is demonstrated for two solutions of the same radical that DAR is temperature independent, in contrast to previously published data.

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The study of rotational mobility of stable nitroxyl radicals in polyvinylacetate
✍ A.M. Wasserman; T.A. Alexandrova; A.L. Buchachenko πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 309 KB

Abstrac~Analyses of the rotational diffusion characters of free and bonded nitroxyt radicals in polyvinylacetate were carried out. The radical rotational character essentially depends on the molecular sizes of the radicals. The movement of the "small" radical is matched by the arbitrary jump tumblin