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A method for the preparation of 3-ketoacyl-CoA derivatives

โœ Scribed by Colin Thorpe

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
317 KB
Volume
155
Category
Article
ISSN
0003-2697

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โœฆ Synopsis

A new method for the preparation of 3-ketoacyl-CoA thioesters (from malonylsemialdehyde to long-chain and phenylpropanoic 3-keto derivatives) is described. It utilizes the facile, thermodynamically very favorable, hydration of 2-alkynoyl-CoA thioesters by enoyl-CoA hydratase. The method is simple and avoids laborious organic syntheses or the use of multicomponent enzymatic methods.

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