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A Method for Palladium-Catalyzed Cross-Couplings of Simple Alkyl Chlorides: Suzuki Reactions Catalyzed by [Pd2(dba)3]/PCy3

โœ Scribed by Jan H. Kirchhoff; Chaoyang Dai; Gregory C. Fu

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
81 KB
Volume
114
Category
Article
ISSN
0044-8249

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## Abstract Reactions of [(ฮท^5^โ€C~5~H~5~)Ru(PRโ€ฒ~3~)~2~(Cl)] with NaBAr~F~ [BAr~F~^โˆ’^=B{3,5โ€[C~6~H~3~(CF~3~)~2~]}~4~^โˆ’^; PRโ€ฒ~3~=PEt~3~ or 1/2Et~2~PCH~2~CH~2~PEt~2~ (depe)] and PR~2~H (R=Ph, a; __t__Bu, b; Cy, c) in C~6~H~5~F, or of related cationic Ru(N~2~) complexes with PR~2~H in C~6~H~5~F, gave t