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A method for calculating capacity factors at different mobile phase compositions and at different temperatures for members of homologous series in reversed-phase high-performance liquid chromatography. III

✍ Scribed by P. Dufek


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
550 KB
Volume
299
Category
Article
ISSN
1873-3778

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✦ Synopsis


The linear dependences of log k' on the carbon chain length, on log(methano1 concentration) and on the reciprocal of absolute temperature in reversed-phase highperformance liquid chromatography of homologous series have been used as a basis for deriving equations for calculating the capacity factors of any member of a homologous series at any mobile phase composition and at any temperature. Good agreement was observed between the published and re-calculated data.