A metal (51V, 55Mn, 59Co) NMR investigation of the electron-deficient complexes V(CO)3tmpo, Mn(CO)3tmpo and Co(CO)2tmpo (tmpo = 2,2,6,6-tetramethylpiperidyl-1-oxyl)
โ Scribed by Dieter Rehder; Peter Jaitner
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 431 KB
- Volume
- 329
- Category
- Article
- ISSN
- 0022-328X
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๐ SIMILAR VOLUMES
Based on an activation model, a available scheme to calculate the rate of the electron-transfer reaction between transition-metal complexes in aqueous solution is presented. Ab initio technique is used to determine the electron-transfer reactivity of the type M(H 2 O) 2+/3+ 6 of transition-metal com
The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.