A ‘meta effect’ in the fragmentation reactions of ionised alkyl phenols and alkyl anisoles
✍ Scribed by Guy Bouchoux; Michel Sablier; Tetsuo Miyakoshi; Takashi Honda
- Book ID
- 112133173
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 504 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1076-5174
- DOI
- 10.1002/jms.2977
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The dissociation of protonated alkyl benzoates (para H, CN, OMe and NO~2~) into protonated benzoic acids and alkyl cations was studied in the gas phase. It was found that the product ratio depends on the substituent at the para position of the phenyl ring. The substituent effect is prob
## Abstract The unstrained 3‐chloroalcohols **1a**, **2a** and **3a** do not undergo solvolytic fragmentation in neutral and weakly acidic 80% ethanol, only substitution and elimination products being formed by the limiting __S__~__N__~__1__‐__E1__ mechanisms. This also applies to the corresponding