A Mesoporous Metal−Organic Framework with Permanent Porosity

✍ Scribed by Wang, Xi-Sen; Ma, Shengqian; Sun, Daofeng; Parkin, Sean; Zhou, Hong-Cai

• Book ID: 118221821
• Publisher: American Chemical Society
• Year: 2006
• Tongue: English
• Weight: 148 KB
• Volume: 128
• Category: Article
• ISSN: 0002-7863
• DOI: 10.1021/ja066616r

✦ Synopsis

Recent studies in metal-organic frameworks (MOFs) 1 have focused on the construction of MOFs with permanent porosity for gas storage, 2 separation, 3 and catalysis. 4 These applications hinge on two important properties of MOFs: porosity and stability. So far, almost all reported open MOFs are microporous (with pore sizes <2 nm). The augmentation of their channel sizes to meso-