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A mechanistic test for reactions catalyzed by lewis acids

✍ Scribed by Pierre Laszlo; Michelle Teston-Henry

Book ID
108381440
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
116 KB
Volume
32
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

On the mechanism of Dielsβ€”Alder reaction
On the mechanism of Dielsβ€”Alder reactions catalyzed by Lewis acids
✍ V. Branchadell; A. Oliva; J. Bertran πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 261 KB

The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration.