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A mechanistic study on kinetic compensation effect during low-temperature oxidation of coal chars

โœ Scribed by Kongvui Yip; Esther Ng; Chun-Zhu Li; Jun-Ichiro Hayashi; Hongwei Wu


Book ID
108255376
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
344 KB
Volume
33
Category
Article
ISSN
1540-7489

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The effect of preoxidation of two highly caking coals in the temperature range 120-250ยฐC on weight loss during pyrolysis in a N2 atmosphere up to 1000ยฐC and reactivity of the resultant chars in 0.1 MPa air at 470ยฐC has been investigated. Preoxidation markedly enhances char reactivity (by a factor of

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## Abstract The kinetic compensation effect (KCE) is a wellโ€known behavior pattern wherein a set of related reactions show a linear relationship between the calculated Arrhenius parameters, log~10~ __A__ and __E__~a~. Although various theoretical explanations have been advanced, none has yet found