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A mechanistic study of the dynamic quenching of the excited state of europium(iii) and terbium(iii) macrocyclic complexes by charge- or electron transfer

✍ Scribed by Kielar, Filip; Montgomery, Craig P.; New, Elizabeth J.; Parker, David; Poole, Robert A.; Richardson, Siobhan L.; Stenson, Philip A.


Book ID
118750449
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
222 KB
Volume
5
Category
Article
ISSN
1477-0520

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Electron transfer (ET) to Rh(III) complexes intercalated in DNA is known to initiate the photorepair of cyclobutane-type pyrimidine photodimers Pyr<>Pyr. We analyzed the energetics of the elementary steps of the resulting splitting reaction Pyr<>Pyr + Rh(III) + hΞ½ β†’ Rh(III) + 2Pyr based on results o