𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A mechanistic kinetic model for the initiated anionic polymerization ofϵ-caprolactam

✍ Scribed by R. A. Cimini; D. C. Sundberg

Publisher
Society for Plastic Engineers
Year
1986
Tongue
English
Weight
809 KB
Volume
26
Category
Article
ISSN
0032-3888

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Polymerization of lactams, 92. Non-activ
Polymerization of lactams, 92. Non-activated anionic polymerization of ϵ-caprolactam initiated with the sodium salt of ϵ-caprolactam
✍ Jiří Havlice; Jiří Broz�ek; Monika Šáchová; Václava Nováková; Jan Roda 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 1 views

The non-activated polymerization of e-caprolactam initiated with the sodium salt of e-caprolactam (CLNa), which was prepared in situ with sodium methoxide, was studied in the temperature range 170 -230 8C and at CLNa concentrations from 0.20 to 1.0 mol-%, and at 190 8C in the presence of 2.0 -10.0 m

Polymerization of lactams, 88. Copolymer
Polymerization of lactams, 88. Copolymers poly(ϵ-caprolactam)-block-polybutadiene prepared by anionic polymerization, part III. Model polymerizations initiated with potassium salt of ϵ-caprolactam and accelerated with isocyanates and their derivatives
✍ Roman Sobotík; Radim Šrubař; Jan Roda 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 856 KB

## Abstract Anionic polymerization of ϵ‐caprolactam was initiated with the potassium salt of ϵ‐caprolactam and accelerated with phenyl isocyanate, toluylene diisocyanate, 4,4′‐diphenylmethane diisocyanate, some derivatives of these isocyanates (urethanes, ureas, and allophanates), or combinations o

Anionic polymerization of ϵ-caprolactam—
Anionic polymerization of ϵ-caprolactam—LX. Ionization and solvation changes in the initial stage of the anionic polymerization of lactams in tetrahydrofuran
✍ J. Stehlíček; J. Šebenda 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 465 KB

Interactions between potassium salts of lactams and N-acyllactam propagation centres in the initial stage of the anionic polymerization of lactams were studied by measuring changes in the electric conductivity and in the i.r. spectrum in the range of carbonyl vibration bands of these compounds and o