A mechanistic approach to the thermal degradation of α-olefin sulfonates
✍ Scribed by P. C. Hu; M. E. Tuvell
- Book ID
- 112777768
- Publisher
- Springer-Verlag
- Year
- 1988
- Tongue
- English
- Weight
- 667 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0003-021X
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## Abstract The two‐step alkylation of phenyl prop‐2‐enyl sulfone (1) with protected ω‐bromoalkanols and 1‐iodoalkanes (→3; see __Scheme 1__) followed by a Pd‐catalyzed desulfonylation with LiBH~4~ affords a 96:4 mixture of vinylbranched, protected alcohols and corresponding ethylidene‐branched iso
The thermal degradation of polyisobutylene is characterized by kinetics consisting of four types of intramolecular hydrogen abstraction (back-biting) of primary (p) and tertiary (t) terminal macroradicals (Ri and R;) and the successive scission at the inner position of the main chain. This reaction