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A mechanism of mass spectral ketene elimination from phenyl acetates

✍ Scribed by Hisao Nakata; Akira Tatematsu


Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
110 KB
Volume
5
Category
Article
ISSN
1076-5174

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Comparisons of the mass spectral behaviour of the [M -421 ions from enol acetates and that of the corresponding ketones indicate that the elimination of a ketene molecule from enol acetates proceeded through a four-membered cyclic transition state to afford fragment ions with an enolic structure.

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