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A mechanism for exchange and substitution reactions in platinum(IV) complexes

✍ Scribed by Fred Basolo; P.H. Wilks; R.G. Pearson; R.G. Wilkins


Book ID
118903574
Publisher
Elsevier Science
Year
1958
Weight
75 KB
Volume
6
Category
Article
ISSN
0022-1902

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πŸ“œ SIMILAR VOLUMES


Rates and mechanisms for halide anation
✍ L.I. Elding; L. Gustafson πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 736 KB

The bromide anation of tr-PtCl&H,O-has been studied at 25 "Cand the chloride anations of tr-PtCl,-BrH,O-and PtBrSHzO-at 50 "C, These reactions proceed via halide assisted mechanisms, compatible with the experimental rate laws: -d [tr-PtCl&H,O-] /dt = 0.43 [Br-] \* [ tr-PtClJBrH20-] s-' M-\* -d[tr-Pt