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A measurement of the strength of the ν2 band of CH3

✍ Scribed by J. Wormhoudt; K.E. McCurdy

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
374 KB
Volume
156
Category
Article
ISSN
0009-2614

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✦ Synopsis

The infrared band strength of the Ye band of the methyl radical has been measured using tunable diode laser absorption by the Q8(8) line at 608.3 cm-'. Experiments were performed in a discharge-flow apparatus, using the homogeneous recombination decay to quantify CH, concentrations.

The measured line strength at 300 K is (3.2+ 1.0) x lo-l9 cm-' (molecule/cmZ)-', resulting in a band strength of (2.5 +O.S) x lo&" cm-' (molecule/cm')-'.

This agrees with an earlier value to within the combined en-or limits.

📜 SIMILAR VOLUMES

The 2ν8 Band of CH3CN
The 2ν8 Band of CH3CN
✍ M. Koivusaari; A.M. Tolonen; R. Paso; J. Schroderus; R. Anttila 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 364 KB

The overtone band \(2 \nu_{8}^{0}\) of \(\mathrm{CH}_{3} \mathrm{CN}\) around \(720 \mathrm{~cm}^{-1}\) has been measured on a Bruker Fourier transform spectrometer at a resolution of \(0.003 \mathrm{~cm}^{-1}\). Only the parallel band was observed, but due to the \(l(2,2)\) resonance, \(\Delta K=-2