Iser-based clwmicsl kinetics technique has been demonstrated in studies of the reaction of 011 with C2114\_ The rcxtwn mcchnism is dominated by elcctrophtlic addition of OH to the double bond at low temperatures, and by increasing-I\ rApid decomposition of the thcrmalized adduct iiOC2t-l.~ back to r
β¦ LIBER β¦
A master equation study of laser-generated interference in the detection of hydroxyl radicals using laser-induced fluorescence
β Scribed by Zeng, Guang; Heard, Dwayne E.; Pilling, Michael J.; Robertson, Struan H.
- Book ID
- 119651892
- Publisher
- American Geophysical Union
- Year
- 1998
- Tongue
- English
- Weight
- 522 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1944-8007
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## Abstract The laser photolysisβlaserβinduced fluorescence method was used for measuring the kinetic parameters of the reaction of OH radicals with CF~3~CH~2~OCH~2~CF~3~ (2,2,2βtrifluoroethyl ether), in the temperature range of 298β365 K. The bimolecular rate coefficient at 298 K, __k__~II~(298),