A Mass Spectral Study of exo- and endo-2-Norbornyl Bromides 1
✍ Scribed by DeJongh, D. C.; Shrader, S. R.
- Book ID
- 126206505
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 259 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
The effect of substituents at C4, 5, 6 and 7 on solvolysis rates and products of 2-exo-and 2-endo-norbornyl tosylates confirms that differential carbon participation is responsible for varying exo/endo rate and product ratios.
## Abstract A PE‐spectroscopic study of __exo__‐ and __endo__‐2‐norbornyl iodides suggests that the relative ability of the 2‐norbornyl group to stabilize an electron deficiency on a substituent X (e.g. I) in __exo__‐ or __endo__‐position depends on the location of the positive charge. There is __n
## Abstract The solvolysis rates and products of the 6‐__exo__‐substituted 2‐__exo__‐ **1a**‐**1u**, and 2‐__endo__‐norbornyl __p__‐toluenesulfonates **2a**‐**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants σ of