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A low-energy crossed-beam study of the hydride abstraction and charge transfer reactions of C+ with CH3OH

โœ Scribed by R.A. Curtis; J.M. Farrar

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
493 KB
Volume
123
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

We present a study of the hydride abstraction and charge transfer reactions of Ct with CH,OH in the relative energy range from 1.2 to 2.8 eV. Both reaction processes are direct in this collision energy range. The charge transfer reaction proceeds through large impact parameter collisions; the kinetic energy distributions indicate that the final product vibrational states are energy resonant with the recombination energy of the carbon cation. The hydride abstraction channel is a stripping reaction in which the product kinetic energy distributions have an unusual Gaussian shape, suggestive of the projection of the ground vibrational state wavefunction for the breaking C-H bond onto the continuum wavefunction associated with separation of the nascent products.

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