Vibrational Excitations of Methane in th
β
R. Lemus; A. Frank
π
Article
π
2000
π
Elsevier Science
π
English
β 263 KB
The stretching and bending vibrations of methane are described in a local-mode anharmonic symmetry adapted model. Both Hecht-and Fermi-like interactions are considered. We start by establishing the Hamiltonian of the system in terms of internal coordinates and momenta. The Hamiltonian is then rewrit