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A local mode description of anharmonic vibrational excitations in linear molecules

✍ Scribed by R. Lemus; A. Frank


Book ID
108430786
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
123 KB
Volume
242
Category
Article
ISSN
0301-0104

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Vibrational Excitations of Methane in th
✍ R. Lemus; A. Frank πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 263 KB

The stretching and bending vibrations of methane are described in a local-mode anharmonic symmetry adapted model. Both Hecht-and Fermi-like interactions are considered. We start by establishing the Hamiltonian of the system in terms of internal coordinates and momenta. The Hamiltonian is then rewrit