A linear homotrinuclear nickel(II) complex with a reduced ONNO-type Schiff base
✍ Scribed by Arıcı, Cengiz ;Yüzer, Devrim ;Atakol, Orhan ;Fuess, Hartmut ;Svoboda, Ingrid
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 256 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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In the crystal structure of the centrosymmetric title complex, bis the Mn atom adopts a trigonal-bipyramidal geometry and the ligand adopts two coordination modes, monodentate and bidentate bridging.
The Schi base nickel complex functionalised with hydroxyl groups, N ; N H -ethylene-bis-(4-hydroxysalicyliminate)nickel(II), [Ni(4-HOsalen)], was anchored onto an air-oxidised activated carbon using cyanuric chloride (CC) as the linking agent. Complex anchoring was made in three consecutive steps: (