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A laser flash photolysis study of the reactivities of the triplet states of 8-methoxypsoralen and 4,5′,8-trimethylpsoralen with nucleic acid bases in solution

✍ Scribed by Paul C. Beaumont; Barry J. Parsons; Glyn O. Phillips; John C. Allen


Book ID
115747246
Publisher
Elsevier Science
Year
1979
Weight
502 KB
Volume
562
Category
Article
ISSN
0005-2787

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The photochemistry of maleimide in aqueous solution is governed by the coexistence of up to three different triplet states, the keto triplet (lambda(max)=250, 330 nm, lambda(min)=290 nm, pK(a)=4.4+/-0.1, tau=5 micros), the deprotonated or enolate triplet (lambda(max)=360, 260 nm, lambda(min)=320 nm,