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A laser flash photolysis study of dibenzocycloheptadienylidene

✍ Scribed by L.M. Hadel; M.S. Platz; B.B. Wright; J.C. Scaiano


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
431 KB
Volume
105
Category
Article
ISSN
0009-2614

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✦ Synopsis


Laser flash photolysis of dia~odibenzocyclohaptadiene gives the title carbene which is readily observed and which reacts by hydrogen abstraction to give the corresponding radical.


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## Abstract Chloranil (2,3,5,6‐tetrachloro‐2,5‐cyclohexadiene‐1,4‐dione; **C**) in deoxygenated acetonitrile shows transient absorptions which are assigned to the radical anion \documentclass{article}\pagestyle{empty}\begin{document}$ \rm {C}^{- \kern-4pt {.}} $\end{document} and to the triplet ^3^