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A kinetics study of the homogeneous and heterogeneous components of the HCl + ClONO2 reaction

โœ Scribed by Friedl, Randall R.; Goble, James H.; Sander, Stanley P.

Book ID
119707703
Publisher
American Geophysical Union
Year
1986
Tongue
English
Weight
358 KB
Volume
13
Category
Article
ISSN
1944-8007

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The kinetics of the reaction between CH3 and HCI was studied in a tubular reactor coupled to a photoionization mass spectrometer. Rate constants were measured as a function of temperature (296-495 K) and were fitted to an Arrhenius expression: kl = 5.0(+-0.7) x exp{-1.4(+0.3) kcal mol-'/RT} cm3 mole