A kinetic study of the copper-catalysed oxidative coupling of 2,6-dimethylphenol. The role of copper, base and phenol concentrations
β Scribed by Patrick J. Baesjou; Willem L. Driessen; Ger Challa; Jan Reedijk
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 144 KB
- Volume
- 135
- Category
- Article
- ISSN
- 1381-1169
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π SIMILAR VOLUMES
The ligands bipyridine (bpy), 4,4 -dimethoxy-2,2 -bipyridyl (dMeObpy), 4,4 -dimethyl-2,2 -bipyridyl (dMebpy), 4,4dichloro-2,2 -bipyridyl (dClbpy) and 4,4 -dinitro-2,2 -bipyridyl (dNO 2 bpy), when combined with copper(II) nitrate render active catalysts. The highest activity was found for bpy as the
## Abstract Polyphenylene oxide (PPO) was prepared via oxidative coupling polymerization of 2,6βdimethylphenol (DMP) catalyzed by copper salt. The ligand was a novel series of random copolymers (PSVP) of styrene and 4βvinylpyridine prepared by reversible additionβfragmentation chain transfer (RAFT)