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A kinetic study of the chlorination of tertiary alcoholamines in alkaline media

✍ Scribed by J. M. Antelo; F. Arce; J. L. Armesto; A. Garcia-Verdugo; F. J. Penedo; A. Varela

Publisher: John Wiley and Sons
Year: 1985
Tongue: English
Weight: 572 KB
Volume: 17
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550171109

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✦ Synopsis

The kinetics of the chlorination of various tertiary alcoholamines by hypochlorite have been studied in alkaline media. A reaction mechanism consistent with the experimental results is put forward, and a relationship is established between the rate constants and the polar parameter (%*) of the substituents.

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