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A kinetic study of Pd–Au catalyzed synthesis of vinyl acetate from oxidation of ethylene and acetic acid in heterogeneous gas reaction

✍ Scribed by Motahari, Kazem ;Atashi, Hossein ;Fazlollahi, Farhad ;Tabrizi, Farshad F. ;Sarkari, Majid


Book ID
113716518
Publisher
Elsevier
Year
2012
Tongue
English
Weight
435 KB
Volume
18
Category
Article
ISSN
1226-086X

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The Use of DRIFTS-MS and Kinetic Studies
✍ S.M. Augustine; J.P. Blitz 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 645 KB

Supported palladium catalyzes the synthesis of vinyl acetate (VA) by oxyacetylation of ethylene. Alkali promoters increase activity and selectivity. The role of acetic acid ( \(\mathrm{HOAc}\) ) in these processes is not well understood. Activation energy studies show that HOAc alters the catalyst s