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A kinetic model of the first intercalation of graphite

✍ Scribed by K.K. Bardhan; D.D.L. Chung

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
1014 KB
Volume
18
Category
Article
ISSN
0008-6223

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✦ Synopsis

model of first rapid intercalation is presented to describe the kinetics of intercalation. The model applies to interface-controlled intercalation, as for the intercalation of Br, and other similar intercalates. In this model, intercalation proceeds by layer-by-layer nucleation and subsequent in-plane growth: a time gap is assumed between the nucleation of two successive intercalate layers. The model has been applied to analyze the variation of the surface and thickness profiles and mass increase during intercalation.

Support of the model by relevant experimental results is discussed.

πŸ“œ SIMILAR VOLUMES

Surface profilometric study of the kinet
Surface profilometric study of the kinetics of the intercalation of graphite
✍ K.K. Bardhan; D.D.L. Chung πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 606 KB

The kinetics of the intercalation of graphite was investigated by measuring the c-face surface profiles during the intercalation of Br, into highly-oriented pyrolytic graphite cylindrical discs at room temperature. A sharp intercalate front was observed to advance while the surface profile evolved f

A simple model of the a-axis conductivit
A simple model of the a-axis conductivity in graphite intercalation compounds
✍ John E. Fischer πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 324 KB

A simple c~c~ation, based on the effective mass ~prox~ation and assu~ng a purely ho-d~ension~ Fermi surface, is performed to estimate the dependence of a-axis conductivity cr, upon intercalant concentration X in the lamellar compounds of graphite. The predicted behavior ob. -X'n is in approximate ag