Based on conceptual models for the stages in the hydration of trlcalcium silicate, a mathematical model was developed. The separate resistances in the mathematical model correspond to the phenomenological stages of the conceptual model. Comparison of model output with available hydration data gave a
A kinetic model for the hydration of tricalcium silicate
β Scribed by Paul Wencil Brown; James Pommersheim; Geoffrey Frohnsdorff
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 378 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0008-8846
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β¦ Synopsis
A kinetic model describing the hydration of C3S has been developed.
The model is predicated on the assumption that the formation of a final hydrate phase initiates in transient hydrate layers which surround the anhydrous grains. This transformation results in the onset of the acceleratory period. The model predicts C-S-H formation to be controlled by interfacial processes during the acceleratory period and by diffuslonal processes thereafter and that the growth of particles is essentially one-dimensional throughout the course of both the acceleratory and post-acceleratory periods.
π SIMILAR VOLUMES
Hydration of C3S in salt solutions having ions in common with its hydration products was investigated by calorimetry and aqueous phase analyses. Soluble calcium salts, which depress hydroxyl ion concentrations in solution by promoting Ca(OH) 2 precipitation, were observed to accelerate hydration. Ac