## Abstract Mephenesin is being used as a centralโacting skeletal muscle relaxant. Oxidation of mephenesin by bis(hydrogenperiodato)argentate(III) complex anion, [Ag(HIO~6~)~2~]^5โ^, has been studied in aqueous alkaline medium. The major oxidation product of mephenesin has been identified as 3โ(2โm
A kinetic investigation of the oxidation ofdl-pipecolinate by bis(hydrogenperiodato)argentate(III) complex anion
โ Scribed by Hongmei Shi; Shipeng Liu; Shigang Shen; Shuying Huo; Weijun Kang
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 342 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
Oxidation of L-proline by bis(hydrogen periodato)argentate(III) complex anion, [Ag(HIO 6 ) 2 ] 5-, has been studied in aqueous alkaline medium in the temperature range of 25-40 โ by use of conventional spectrophotometry. Under the conditions for kinetic measurements, the oxidation results in decarbo
The kinetics of the oxidation of hydroxylamine by manganese(III)-bis(salicylaldimine) complexes have been studied over the 5.2-8.4 pH range. The reaction is first order in both hydroxylamine and oxidant, and inversely proportional to I-H+]. The [complex]: l-hydroxylamine] stoichiometric ratio is 1:1
## Abstract A comparative kinetic study of the reactions of two mixed valence manganese(III,IV) complexes with macrocyclic ligands, [L^1^Mn^IV^(O)~2~Mn^III^L^1^], **1** (L^1^ = 1,4,7,10โtetraazacyclododecane) and [L^2^Mn^IV^(O)~2~Mn^III^L^2^], **2** (L^2^ = 1,4,8,11โtetraazacyclotetradecane) with 2