A kinetic investigation of the gas-phase reactions of hydroxyl radicals with cyclic ketones and diones: mechanistic insights
β Scribed by Dagaut, Philippe; Wallington, Timothy J.; Liu, Renzhang; Kurylo, Michael J.
- Book ID
- 117988376
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 382 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M
The gas-phase reaction of NO 3 radicals with isoprene was investigated under flow conditions at 298 K in the pressure range 6.8 Ο½ P(mbar) Ο½ 100 using GC-MS/FID, direct MS, and long-path FT-IR spectroscopy as detection techniques. By means of a relative rate method, the rate constant for the primary