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A kinetic investigation of styrene/ethyl acrylate copolymerization

✍ Scribed by N. T. McManus; A. Penlidis

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
859 KB
Volume
34
Category
Article
ISSN
0887-624X

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✦ Synopsis

An experimental study of the bulk-free radical copolymerization of styrene (STY)/ethyl acrylate (EA) initiated by 2,2'-azobisisobutyronitrile was conducted. Reactivity ratios were evaluated using both nonlinear least-squares (NLLS) and error-in-variables model (EVM) techniques. A thorough study of the kinetics over the full conversion range was subsequently carried out at a variety of feed compositions, initiator concentrations, and temperatures, with and without added chain transfer agent (CTA).

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