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A kinetic approach to acrylamide radical polymerization by horse radish peroxidase-mediated initiation

✍ Scribed by Lalot, Thierry; Brigodiot, Maryvonne; Maréchal, Ernest

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 120 KB
Volume: 48
Category: Article
ISSN: 0959-8103
DOI: 10.1002/(sici)1097-0126(199904)48:4<288::aid-pi145>3.0.co;2-i

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✦ Synopsis

Free-radical polymerization of acrylamide in water at room temperature involves catalysis by horse radish peroxidase to produce radical species from hydrogen peroxide and 2,4-pentanedione through an oxidoreductive pathway. In the presence of the vinylic monomer, initiation takes place, leading to polyacrylamide formation after a long and unreproducible inhibition period. Conversiontime plots are presented, and some kinetic features are compared with results of previous studies of classical acrylamide polymerization.

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