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A justification for the use of the Langer modification in Miller's classical analog method of non-adiabatic scattering

✍ Scribed by Michael F. Herman; Robert Currier

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
363 KB
Volume
114
Category
Article
ISSN
0009-2614

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✦ Synopsis

The analytical behavior of the S matrix in hi&x's classxal anaiog method for electroruc degrees of freedom in nonadiabatic scattermg is considered. It is demonstrated that the L-anger modlfiuhon, wiuch replaces the action vannbks nk with nk f 4, resplrs in an acceptable functional form at the singular pomts u the classxal equations of motion govermng this method. if the Langer modification IS not made, or if the actron variables are shBed by other than half mtegers, then the S matnx does not behave reasonably at these points.

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