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A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure ofcis-[Ru(bpy)2{PPh-(o-tolyl)2}Cl+][ClO4−]·CH2Cl2·H2O

✍ Scribed by Melvyn Rowen Churchill; Lynn M. Krajkowski; My Hang Vo Huynh; Kenneth J. Takeuchi


Publisher
Springer
Year
1996
Tongue
English
Weight
421 KB
Volume
26
Category
Article
ISSN
1572-8854

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✍ Bembenek, Eberhard ;Crespo, Olga ;Concepción Gimeno, M. ;Jones, Peter G. ;Laguna 📂 Article 📅 1994 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 549 KB

Silver(1) complexes I Bis(diphenylphosphany1)-o-carborane I o-Carborane Silver(1) perchlorate or nitrate react readily with bis(di-phenylphosphany1)-o-carborane to give the complexes [AgX((PPh2)2C2BloHlo)1 [X = C104 (l), NO3 (2)]. The perchlorate ligand is weakly bound to the silver atom and thus ca